FDJ-Suez Vollering took the red shirt to the leader by winning in the other mountainous stage in the race on Thursday.
“I am very happy because I can win both mountainous stages,” said Volling, who moved to the FDJ from SD-Worx this season.
“My team was very strong, very strong, and we were always in control. I am really happy with the entire performance with the entire team.”
Van Der Breggen, who returned to the competition this year after his retirement in 2021, began on the second day and led a lot of 10.3 kilometers in rain on the road 152 km from La Robla to Cotobello.
But she had no answer to the Volang explosive attack with about 800 meters to go, as she left Raiser.
Volleting has now won three main tour titles in women's bike riding, after she won Tour De France Femmes for 2023 to go with her victories in Vuelta.
It also included its second victory for the race every individual stage won by the Dutch contestant.
After the American uniform Lidel-Trek obtained the trial of the opening team, Marianne Foss won the second and sixth stages, and Van der Brigon won the fourth stage and
